201 SN1 mechanism HL

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Understandings: • SN1 represents a nucleophilic unimolecular substitution reaction. • SN1 involves a carbocation intermediate. • For tertiary halogenoalkanes the predominant mechanism is SN1 • The rate determining step (slow step) in an SN1 reaction depends only on • the concentration of the halogenoalkane, rate = k[halogenoalkane]. • SN1 reactions are best conducted using protic, polar solvents. • Applications and skills: • Deduction of the mechanism of the nucleophilic substitution reactions of halogenoalkanes with aqueous sodium hydroxide in terms of SN1 and SN2 mechanisms. • Outline of the difference between protic and aprotic 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