TEMA 1 ALCANOS 15 PROYECCION DE NEWMAN

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¿Qué es una proyección de Newman? • La proyección de Newman se obtiene al mirar la molécula a lo largo del eje • C-C. El carbono frontal se representa por un punto, del que parten los tres • enlaces que lo unen a los sustituyentes. El carbono de atrás se representa • por un círculo y los enlaces que salen de este carbono se dibujan a partir • de este círculo. • Proyección de Newman del etano alternado y eclipsado • Las conformaciones del etano se pueden representar fácilmente con esta • proyección. En el caso de la conformación eclipsada para hacer mas • visibles los tres hidrógenos posteriores, éstos se dibujan ligeramente • girados respecto a la posición totalmente eclipsada. • Proyección de Newman para las conformaciones del butano • En la columna derecha se incluyen las conformaciones sin, anti y gauche • del butano, con sus respectivas proyecciones de Newman, en las que se • pueden observar las interacciones entre grupos metilo. La conformación • más estable es la anti (no presenta repulsiones metilo-metilo), siendo la • conformación sin la de mayor inestabilidad (energía elevada) debido al • eclipsamiento 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