From Tshirt to waterproof wonder material Headline Science











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Most of our clothing contains polyethylene terephthalate (PET) fibers, a common form of plastic. Recouping PET fibers from discarded clothing, however, can be costly and toxic, often releasing forever chemicals found in the fabric. But researchers have developed a sustainable way to upcycle textile waste by directly incorporating clothing scraps into a synthesis for metal-organic-frameworks (MOFs). • The PET-to-MOF pipeline is not a new area of study, but a typical MOF synthesis can require very high heat, very high pressure and harsh solvents. This new synthetic pathway can be done at room temperature with eco-friendly solvents. It also turns the MOF superhydrophobic. This well-known MOF, UiO-66, is typically a brittle, hydrophilic substance. But spandex fibers in the fabric functionalize UiO-66 to be completely water resistant. This results in a waterproof coating that can adhere to textiles. Since most waterproofing methods rely on fluorinated chemicals, which are harmful to both the environment and humans, this work provides a sustainable way to create MOF-based, waterproof coatings and to give old clothing a new life. • Read the paper: https://doi.org/10.1021/acsami.4c10459 • (Corresponding author: Juan P. Hinestroza, Ph.D.) • Video credits: • Written, edited and narrated by Vangie Koonce • Produced by Vangie Koonce and Andrew Sobey • Executive produced by Matthew Radcliff • Research videos from Yelin Ko • Additional Video: ChemTube3D by Nick Greeves, Chris Wilmer, Getty Images and • Patrick Fuller • Music: “Pizz and Pieces (Instrumental)” by Richard Morson from Triple Scoop Music. • Sound effects: Soundsnap • Produced by the American Chemical Society (ACS), one of the world’s largest scientific societies. ACS is a global leader in providing access to chemistry-related information and research through its multiple databases, peer-reviewed journals and scientific conferences. • Join the #AmericanChemicalSociety! https://bit.ly/Join_ACS • #plastic #recycling #metal #organic #chemistry

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