Radical Photochemical Deoxygenation











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Interested in boosting success rates in synthesis route design and prediction using the Predictive Retrosynthesis Tool from Reaxys? Find out more information here - https://www.elsevier.com/solutions/re... • Important Papers covers various chemical reactions, mechanisms, and research papers in the field of organic chemistry, providing examples and explanations for each research paper. • In this video, I discuss five important papers in organic synthesis that were published around April 2023. • Make sure you share this series with other chemists in your network, especially ones who don't usually watch YouTube! • Support the Channel on Patreon -   / thatchemist   • Join the Community Discord! -   / discord   • Backup Discord link -   / discord   • Important Papers Playlist -    • Important Papers   • ----------------------------------------- • References: • First Paper (Diethanolamine Boronates) - https://pubs.acs.org/doi/10.1021/acs.... • Second Paper (Sulfones via Sulfonyl Fluorides) - https://pubs.acs.org/doi/pdf/10.1021/... • Third Paper (Deoxygenation of Alcohols) - https://doi.org/10.1002/anie.202300178 • Fourth Paper (Room Temp Ar-Br Amination) - https://doi.org/10.1021/jacs.3c00500 • Fifth Paper (Desymmetrization of Boronates) - https://doi.org/10.1021/jacs.3c01571 • ----------------------------------------- • Honorable mentions: • Total Synthesis of (+)-Pedrolide - https://doi.org/10.1021/jacs.3c02113 • Molybdenum(VI) Amide Activation - https://doi.org/10.1021/acs.joc.3c00218 • Diastereoselective Synthesis of Cyclopropanes - https://doi.org/10.1002/ange.202303032 • Tris(bicyclo[1.1.1]pentyl)phosphine - https://doi.org/10.1021/jacs.3c00885 • Total Synthesis of Strempeliopidine - https://doi.org/10.1021/jacs.2c13146 • Sulfonylation of Aryl Bromides - https://doi.org/10.1002/anie.202217623 • Grayanane Diterpenoids - https://doi.org/10.1021/jacs.3c00753 • Mechanochemical Birch - https://doi.org/10.1002/anie.202217723 • Compact Rotaxane Superbases - https://doi.org/10.1021/jacs.3c01202 • Dearomatization of arenes with tetrazinediones - https://doi.org/10.1021/jacs.3c02556 • Enantioselective Divergent Syntheses of Cephalotaxus Alkaloids - https://doi.org/10.1021/jacs.3c01572 • One-Bond-Nucleophilicity and -Electrophilicity Parameters: An Efficient Ordering System for 1,3-Dipolar Cycloadditions - https://pubs.acs.org/doi/full/10.1021... – Mayr paper • Mayr’s N-parameter Database - https://www.cup.lmu.de/oc/mayr/reakti... • Waveform-controlled Electrosynthesis - https://doi.org/10.1126/science.adf4762

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