Youtor
15 Metals and Catalysis in Alkene Oxidation Hydrogenation Metathesis and Polymerization
>> YOUR LINK HERE: ___ http://youtube.com/watch?v=pNSWJkZoSQw
Freshman Organic Chemistry II (CHEM 125B) • • Alkenes may be oxidized to diols by permanganate or by OsO4 catalysis. Metal catalysts provide orbitals that allow simultaneous formation of two bonds from metal to alkene or H2. Coupling such oxidative additions to reductive eliminations, provides a low-energy catalytic path for addition of H2 to an alkene. Such catalytic hydrogenation is often said to involve syn stereochemistry, but the primary literature shows that addition can be anti when allylic rearrangement occurs on the catalyst. Similar oxidative/reductive cycles operate in olefin metathesis and metal-catalyzed polymerization. Careful catalyst design allows control over polymer stereochemistry (tacticity). Polymerizations catalyzed by free-radicals or acids typically lack stereochemical control, but there are ways to control regiochemistry and chain length. Latex, a natural polymer, coagulates to form a rubber ball. • • 00:00 - Chapter 1. Alkene Dihydroxylation • 04:28 - Chapter 2. Catalytic Hydrogenation of Alkenes: Oxidative Addition, Reductive Elimination • 15:08 - Chapter 3. Catalytic Hydrogenation of Alkenes: Stereochemistry • 25:50 - Chapter 4. Olefin Metathesis, Polymerization, and Tacticity • 39:00 - Chapter 5. Radical Polymerization • 43:16 - Chapter 6. Electrophilic Oligomerization and Polymerization and Rubber • • Complete course materials are available at the Open Yale Courses website: http://oyc.yale.edu • • This course was recorded in Spring 2011.
#############################
