Youtor
Aldol Addition Reactions with Lithium amp Proline IOC 21
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Disclaimer LDA can also afford E-enolates, and usually a mixture is obtained; if an ester or an amide is used instead of a ketone, the selectivity can change! Depending on the ketone that is used, the selectivity can also reverse. • ---------------------------------------------------------------------------------------------------------------------------------- • Links to articles discussed in this episode: • first lithium aldol - https://doi.org/10.1039/D0SC06223E • second lithium aldol - https://doi.org/10.1002/chem.201502754 • Ben List - https://doi.org/10.1021/ja994280y • Nobel Prize - https://www.nobelprize.org/prizes/che... • proline aldol example - https://doi.org/10.1126/science.abb3231 • ---------------------------------------------------------------------------------------------------------------------------------- • I hope you enjoyed the video! I'm planning on making a full series of videos if these videos are helpful for people! • Recommended Texts: • J. Clayden, N. Greeves, S. Warren, Organic Chemistry Second Edition, Oxford University Press, 2012. (especially good for mechanism and physical chemistry explanations) • T. W. G. Solomons, C. B. Fryle, S. A. Snyder, Organic Chemistry Twelfth Edition, Wiley-VCH Verlag GmbH Co. KGaA, 2016. • LibreTexts: • https://chem.libretexts.org/Bookshelv...
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