Stability of Geminal diol Gemdiol

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#Geminaldiol, #Gemdiol, #dialcohol, #carbonyl, #Hydrogenbond, #Chloralhydrate, • • In this video, I shall discuss the stability of germinal diol. Actually, the equilibrium between the carbonyl group (C=O) and Gem-diol prefers to remain in the left side. Consequently, the percentage of the carbonyl group (C=O) in the equilibrium is more. However, changing the controlling factors like electron deficiency of the substituent attached with carbonyl group and further stabilization of the produced di alcohol (OH) by hydrogen bonding shifts the equilibrium towards the right side. I have discussed these phenomena through various examples which may be helpful for basic understanding from the molecular interaction point of view. • Links for some related videos are given below. Please watch them for a better understanding. • For Video Lecture 5 (part II): Reactivity of borohydrides (MBH4) [mainly organic reactions]. please click on the link Video Lecture: 5 (part I), Preparation, Bonding and Reactivity reactions) of borohydrides (MBH4). • For Question Answer discussion about Luche reaction (for CSIR-NET, GATE, JAM) please click on the link • Question Answer discussion about Luch... • For Luche Reaction, selective reduction of ketone into secondary (2o) alcohol. please click on link • Luche Reaction, selective reduction o... • For Wacker process for conversion of ethylene to acetaldehyde. please click on the link • Wacker process for conversion of ethy... • For Lindlar Catalyst, selective reduction of alkyne to cis-alkene. please click on the link • Lindlar Catalyst: selective reduction... . • • For Stability of Geminal diol (Gem-diol). please click on the link • Stability of Geminal diol (Gem-diol).

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